No, it isn't possible. The reasons are quite simple:1. If there was so much air or space or whatever in there, everything else would collapse into it because of gravity. There's nothing holding it out that would be nearly strong enough to do so.2. If that was the case, the Earth would have less gravity than it does. We know how much gravity the Earth has, so we can tell it isn't hollow.3. We've used sonar devices to send shockwaves through the Earth and measure the ways in which they bounce around inside. If the Earth was hollow, this would show up very clearly on the instruments. However, the instruments show nothing indicating that.